Adsorption Mechanism and Kinetic Characterization of Bituminous Coal under High Temperatures and Pressures in the Linxing-Shenfu Area

The majority of coalbed methane(CBM) in coal reservoirs is in adsorption states in coal matrix pores. To reveal the adsorption behavior of bituminous coal under high-temperature and high-pressure conditions and to discuss the microscopic control mechanism affecting the adsorption characteristics, isothermal adsorption experiments under hightemperature and high-pressure conditions, low-temperature liquid nitrogen adsorption-desorption experiments and CO2 adsorption experiments were performed on coal samples. Results show that the adsorption capacity of coal is comprehensively controlled by the maximum vitrinite reflectance(Ro, max), as well as temperature and pressure conditions. As the vitrinite reflectance increases, the adsorption capacity of coal increases. At low pressures, the pressure has a significant effect on the positive effect of adsorption, but the effect of temperature is relatively weak. As the pressure increases, the effect of temperature on the negative effect of adsorption gradually becomes apparent, and the influence of pressure gradually decreases. Considering pore volumes of pores with diameters of 1.7-100 nm, the peak volume of pores with diameters 10-100 nm is higher than that from pores with diameters 1.7-10 nm, especially for pores with diameters of 40-60 nm, indicating that pores with diameters of 10-100 nm are the main contributors to the pore volume. The pore specific surface area shows multiple peaks, and the peak value appears for pore diameters of 2-3 nm, indicating that this pore diameter is the main contributor to the specific surface area. For pore diameters of 0.489-1.083 nm, the pore size distribution is bimodal, with peak values at 0.56-0.62 nm and 0.82-0.88 nm. The adsorption capability of the coal reservoir depends on the development degree of the supermicroporous specific surface area, because the supermicroporous pores are the main contributors to the specific pore area. Additionally, the adsorption space increases as the adsorption equilibrium pressure increases. Under the same pressure, as the maximum vitrinite reflectance increases, the adsorption space increases. In addition, the cumulative reduction in the surface free energy increases as the maximum vitrinite reflectance increases. Furthermore, as the pressure increases, the surface free energy of each pressure point gradually decreases, indicating that as the pressure increases, it is increasingly difficult to adsorb methane molecules.     

基于2 m格网点云数据的高精度DEM制作第三次国土调查坡度图

地形地貌随着时间的推移时刻发生变化，以高精度数字高程模型（EDE）数据制作坡度图，进而计算田坎系数，更精准地进行耕地面积计算及统计。以2 m格网点云数据生成的DEM数据为基础，按照第三次全国国土调查的相关技术要求，根据耕地坡度分级要求进行分级，生成坡度分级栅格数据图。对坡度分级栅格数据图进行矢量化，生成坡度分级矢量化数据。对矢量化数据进行图斑综合、界线平滑、拓扑重建、数据裁切等处理，制作完成调查区域坡度图及相关属性数据制作。并对生产的坡度图成果进行分析，找出不同尺度格网生产的坡度图的技术差异，并对高精度坡度的应用进行了展望。     

面向地震应急的山区人口百米格网分布——以麟游县为例

破坏性地震发生后，山区易发生滑坡、泥石流等地质灾害。精细化人口空间分布数据能够有效提升灾情评判精度，为应急救援决策提供参考依据。本文以陕西省麟游县为例，利用"天地图"高分辨率遥感影像解译大比例尺居民地数据，结合人口、行政区划等数据，利用GIS（地理信息系统）技术制作100 m×100 m格网人口分布数据。通过与陕西省地震局现有人口空间数据进行对比，发现百米格网人口分布数据可明显提升山区次生灾害影响人口计算结果的可靠性。     

煤层气井产出剖面测试技术及应用

现有常规油气井产出剖面测试方法在煤层气井中适应性较差，测试范围和测量工艺等存在局限性，施工成功率低。因此，本文对煤层气井产出剖面测试技术进行了整体的系统化设计和研发。通过紧凑的结构设计、高度集成，研发了一套可同时进行温度、压力、磁性定位、热式流量、探针持气率、微波持气、涡轮流量和超声流量等多参数测量的煤层气井测井仪，并研制了一套一次下井可进行多种测试技术测量的煤层气井产出剖面测试技术。同时提高了测试仪器的精度和抗干扰能力，开发了多任务多窗口的便携地面系统操作，并研制新型偏心测试井口应用于煤层气井，实现修井作业时不间断连续测试。该技术在鄂尔多斯盆地石楼北区块3口煤层气井进行了现场试验，取得精确、连续的测试数据。测试结果显示，石楼北区块8^#+9^#煤层为主力产气、产水层。     

沁水盆地南部长治区块煤层气田的地应力特征

煤层气的生成、运移及富集等都与地应力的特征有直接的关系,掌握煤储层的应力特征对煤层气田的勘探和开发具有重要意义。基于沁水盆地南部长治区块煤层气开发区18口煤层气井的测井数据,利用带有残余构造应力的Anderson模型,分析垂向应力、最小及最大水平地应力的分布规律。结果表明:垂向应力基本上呈东西走向对称分布,东西部的应力大,中部应力小,数值在15.2~16.5 MPa之间;最小水平主应力自西向东呈现高→低→高→低的分布特点,数值在10.2~19.3 MPa之间;最大水平主应力也是自西向东呈现高→低→高→低的分布,数值在13.0~34.2 MPa之间。研究区东部所受埋深影响大于所受构造影响,而西部受到的构造影响大于其所受的埋深影响。研究区地应力分布规律与煤层气井的产气量存在高度相关性,研究成果可以为煤层气的勘探、开发和安全生产等方面提供参考。     

Deep gold mineralization features of Jiaojia metallogenic belt,Jiaodong gold Province: Based on the breakthrough of 3000 m exploration drilling

Recently, continuous breakthroughs have been made about deep gold prospecting in the Jiaodong gold province area of China. Approximately 5000 t of cumulative gold resources have been explored in Jiaodong, which has thus become an internationally noteworthy gold ore cluster. The gold exploration depth has been increased to about 2000 m from the previous <1000 m. To further explore the mineralization potential of the Jiaodong area at a depth of about 3000 m, the Shandong Institute of Geological Sciences has drilled an exploratory drillhole named “Deep drillhole ZK01” to a depth of 3266 m. Hence, as reported herein, the mineralization characteristics of the Jiaojia metallogenic belt have been successfully documented. ZK01 is, to date, the deepest borehole with an gold intersect in China, and constitutes a significant advance in deep gold prospecting in China. The findings of this study further indicate that the depth interval of 2000 m to 4000 m below the ground surface in the Wuyi Village area incorporates 912 t of inferred gold resources, while the depth interval of 2000 m to 4000 m below the surface across the Jiaodong area possesses about 4000 t of inferred gold resources. The Jiaojia Fault Belt tends to gently dip downward, having dip angles of about 25° and about 20° at vertical depths of 2000 m and 2850 m, respectively. The deep part of the Jiaojia metallogenic belt differs from the shallow and moderately deep parts about fracturing, alteration, mineralization, and tectonic type. The deep zones can generally be categorized from inside outward as cataclastic granite, granitic cataclasite, weakly beresitized granitic cataclasite, beresitized cataclasite, and gouge. These zones exhibit a gradual transitional relation or occur alternately and repeatedly. The mineralization degree of the pyritized cataclastic granite-type ore in the deep part of the Jiaojia metallogenic belt is closely related to the degree of pyrite vein development; that is, the higher the pyrite content, the wider the veins and the higher the gold grade. Compared to the shallow gold ores, the deep-seated gold ores have higher fineness and contain joseite, tetradymite, and native bismuth, suggesting that the deep gold mineralization temperature is higher and that mantle-sourced material may have contributed to this mineralization. ZK01 has also revealed that the deep-seated ore bodies in the Jiaojia metallogenic belt are principally situated above the main fracture plane (gouge) and hosted within the Linglong Granite, contradicting previous findings indicating that the moderately shallow gold ore bodies are usually hosted in the contact zone between the Linglong Granite and Jiaodong Group or meta-gabbro. These new discoveries are particularly significant because they can help correct mineralization prospecting models, determine favorable positions for deep prospecting, and improve metallogenic prediction and resource potential evaluation.     

四川地区多模式2m温度预报性能分析及集成方法研究

本文通过分析2017年9~12月四川地区ECMWF(European Centre for Medium-Range Weather Forecasting)细网格模式、GRAPES_GFS(Global and Regional Assimilation and Prediction System)全球模式和西南区域模式(South West Center-WRF ADAS Real-time Modeling System, SWCWARMS)2m温度168h预报时效内的系统性偏差特征,采用滑动双权重平均法分别对三种模式温度预报产品进行偏差订正,并集成得到各时效2m温度的订正场,结果表明:(1)三种模式的预报存在明显的日变化,整体上EC模式的预报最优。(2)三种模式对于低温和高温的预报,在全省均大致呈现负的系统性误差,特别在高原及过渡区表现的尤为明显。(3)订正后三种模式的预报准确率显著提高,均方根误差减小1.4~2.5℃,大部分地区平均误差维持在±0.5℃之间,在系统性偏差较大的地区,订正效果更好。(4)两种集成方案预报结果接近,且均优于三种模式的订正预报。     

WRF中土壤图及参数表的更新对华北夏季预报的影响研究

土壤质地及其物理性质的参数化对陆面过程模拟具有明显的影响。研究了土壤质地和土壤水文参数表的更新对WRF（Weather Research and Forecasting）模拟性能的影响。使用北京师范大学土壤属性数据集和修正后的土壤水文参数表替换WRF默认数据,对2017年6—8月华北地区开展数值模拟试验和评估验证。结果表明,模拟结果对土壤类型数据集和水文参数表的更新较为敏感,对地面要素预报有正效果。WRF默认土壤数据集中,中国东部以粘壤土为主,而在北京师范大学土壤数据集里则以壤土为主;修正后的土壤水文参数在Noah陆面过程中增强了裸土潜热蒸发能力。数值模拟试验表明,土壤输入数据和土壤水文参数的更新能够增强陆面向大气的潜热同时减弱感热输送,致使大气底层温度降低而湿度增大。利用华北区域748个地面气象观测站的2 m温度和2 m湿度对2017年夏季的模拟结果进行验证,结果显示更新试验对地面要素的预报偏差有较好的修正作用,能够将2 m温、湿度的预报技巧分别提高3.4%和2.9%。      

GRAPES_RAFS系统2 m温度偏差订正方法研究

本文通过对2013年6月20日至7月20日GRAPES(Global and Regional Assimilation and Prediction System)_RAFS(Rapid Analysis and Forecast System)系统每天8个时次每3h的2 m温度预报进行分析,发现各时次的预报均能较好地表征2 m温度日变化特征,但预报与实况存在一定的偏差,其中西藏东部川西高原、云贵高原、江南武夷山脉偏低于实况可达3℃,而华北地区偏高于实况3℃以上.为了减小GRAPES_RAFS系统偏差对2m温度预报的影响,本文采用平均法、双权重平均法、滑动平均法和滑动双权重平均法分别对GRAPES_RAFS系统2 m温度预报产品进行偏差订正,并对订正前后的结果进行检验分析和对比.结果表明:2 m温度订正后的平均误差大部地区减小到(一1～1℃),而均方根误差大部地区降低到2.5℃内.对于偏差较大地区,订正效果更为明显,如西藏东部川西高原,经过订正,平均误差绝对值由订正前3℃以上降低到1℃内,而RMSE由订正前4℃以上控制到3℃内.对比四种订正方法,双权重订正方法与平均法订正整体效果接近,但对个别站点,双权重订正法要优于平均法,经过滑动的订正方法比无滑动的订正方法订正效果更好,订正效果最好的是滑动双权重平均法,全国平均误差大部分在(-0.5～0.5℃)内,不超过(-1～1℃)的范围.     

沈阳大气气溶胶光学特性及其影响因子

利用2010年3—10月沈阳大气成分监测站CE－318太阳光度计观测资料,计算沈阳大气气溶胶光学厚度和波长指数等大气光学特性参数,结合地面气象观测资料,分析大气气溶胶光学特性及其影响因子。结果表明：沈阳气溶胶光学厚度在3—6月较高,8月较低,9—10月气溶胶光学厚度略有增加;除4月和8月外,气溶胶光学厚度与风速基本呈反相关;气溶胶光学厚度与可吸入颗粒物（particulate matter,PM）质量浓度变化趋势基本一致;气溶胶光学厚度日平均值距平的绝对值、改变率均与降水强度成正比;地面能见度与气溶胶光学厚度呈负相关。由气溶胶浑浊度系数计算的能见度在4—6月与实际观测的能见度基本吻合,由气溶胶标高计算的水平能见度整体小于实际观测的水平能见度。